In the opening montage of the show Clinton is wearing a plum colored velvet blazer. Does anyone know where I might find a piece like that?

Since you're asking about Clinton, I'm guessing you're looking for men's jackets.

I did a quick Google search for 'plush blazer mens' and one of the bizrate links was this:
http://www.bizrate.com/mens-su...coats/velvet-blazer/

Men's Wearhouse may have them in colors other than black; I'm not sure of this, though.

This may also help:
http://mensfashion.about.com/o...ss/VelvetBlazers.htm

I didn't see the episode, and I'm not sure of the exact cut and style. I have more unfortunate news: simply Googling "mens velvet/plush jacket plum/purple/violet" doesn't yield a whole lot of colors other than charcoal and black. Even a search for the specific item in TLC's WNTW wardrobe has yielded nil.

I hope the other folks on this forum can be of more help.

If you are talking about the outfit that Clinton is wearing in the show's opening scene (repeated every week) then that was filmed years ago and I doubt those styles would still be available. Season 8 is to begin in January of 2010.